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- Most Famous Former Guest: Louis XIII of France. Château de Brissac, near Saumur and Angers, is one of the Loire Valley’s, and indeed France’s, best known chateaux and sees many day visitors both French and international. With seven floors it is the country’s tallest, and its sheer scale alone makes it quite a jaw dropping sight. It is also though an incredibly beautiful building, an elegant masterpiece of architecture that is still thankfully with us after over 400 years of service to the Dukes of Brissac, with the thirteenth Duke of Brissac being your welcoming host today. The chateau is the Duke and his family’s main home and so, despite the chateau’s vast size (its has a total of 204 rooms) only a number of its bedrooms are available to B&B guests. This makes a stay here feel quite special and even more so when the day visitors disappear in the afternoon and the entire chateau and estate is left to you, your fellow guests and the Duke. THE ACCOMMODATION: You have three choices for overnight stays, all of them suites, with the classic double suite being the pick of the bunch in terms of opulence and sheer romantic beauty. READ MORE